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Journal of Korean Institute of Fire Science and Engineering 2003;17(2):50-55.
Published online June 30, 2003.
The Lower Flash Points of the n-Butanol+n-Decane System
Dong-Myeong Ha , Yong-Chan Choi , Sung-Jin Lee
1Department of Safety Engineering, Semyung University
2Department of Safety Engineering, Semyung University
3Department of Liberal Arts and Science, Semyung University
Abstract
The lower flash points for the binary system, n-butanol+n-decane, were measured by Pensky-Martens closed cup tester. The experimental results showed the minimum in the flash point versus composition curve. The experimental data were compared with the values calculated by the reduced model under an ideal solution assumption and the flash point-prediction models based on the Van Laar and Wilson equations. The predictive curve based upon the reduced model deviated form the experimental data for this system. The experimental results were in good agreement with the predictive curves, which use the Van Laar and Wilson equations to estimate activity coefficients. However, the predictive curve of the flash point prediction model based on the Willson equation described the experimentally-derived data more effectively than that of the flash point prediction model based on the Van Laar equation.
Key Words: Lower Flash Points, Flammable, Pensky-Martens Closed Cup Tester, Reduced Model, Van Laar Equation, Wilson Equation
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